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by
Julian C. Holmes
julianholmes@ibm.net
The use of oxygenated reformulated gasoline (RFG) was established in Maine by Federal and State officials:
..."to control the emissions of Volatile Organic Compounds (VOCs) to reduce their emissions [sic] in order to meet federal and state ozone standards." (Memorandum to Maine Board of Environmental Protection from Donald L. Anderson, Maine Department of Environmental Protection (MDEP), 7/13/95/p.1){4.1
The same reasoning had been used previously to establish CARTEST.
Dirty Air, Dirty Water examines the scientific basis for, discusses limitations of, and reviews the politics leading to the use of CARTEST and the use of oxygenated reformulated-gasoline (RFG) to reduce ozone in Maine. This Report was prepared, originally, for the Maine Legislature Select Committee to Study the Health Effects of Reformulated Gasoline [identified by capital letters in the following text as the "COMMITTEE"].
[The complete set of Findings is Appendix 1.]
Ozone, a molecule comprising three atoms of oxygen, is a gas poisonous to animals, plants, and to people.{5.1 Ozone is generated in the air by primarily warm-weather chemical interactions among three ingredients: VOCs (Volatile Organic Compounds), NOx (Nitrogen Oxides), and sunlight.{5.2 Two of the necessary ingredients, VOCs and NOx, are chemicals generated by man's various activities as well as by plant life.
VOCs are hydrocarbons that evaporate directly from the organic chemicals we use or encounter in daily life -- such as acetone, benzene, gasoline, or fresh asphalt. VOCs are also produced when organic matter is burned as in an incinerator, power plant, wood stove, oil furnace, or a gasoline engine. But most VOCs in Maine's air (92%) are produced in nature by trees.{5.3
Molecules of the second kind are called oxides of nitrogen (NOx). They are mainly combustion products from man's activities. Automobiles, industry, and incineration are major sources of NOx.{5.4
MDEP prepares "inventories" of VOCs and NOx that are emitted into the air in Maine. It is the amounts of ambient VOCs and NOx actually in the air that determine how fast ozone is produced.
Early on, Maine officials committed themselves to VOC-reduction strategies for lowering ozone. Today, some of these officials are understandably less than at ease with the fact that most VOCs in Maine come from trees, not automobiles -- a fact, that for practical purposes, dictates NOx reductions in order to lower ozone.{5.5 The seminal National Research Council reference guide to air-pollution science warns, "The biogenic VOC contribution [from trees] is a background concentration that cannot be removed from the atmosphere by emission controls".{5.6 (CARTEST and RFG are examples of proposals to lower ozone by controlling emissions of VOCs.)
Furthermore, in Maine, the relative abundance of ambient VOCs, compared to NOx, is such that we have often a condition known in atmospheric-chemistry circles, as "NOx-limited"{5.7, again a situation which requires, in order to lower ozone, that NOx be reduced, more so than VOCs. Nevertheless, at MDEP the emphasis is to reduce the concentration of man-made VOCs{5.8 -- which, reduces insignificantly the total VOC inventory which, in turn, will reduce even less significantly our ozone air-pollution.
A January 1993 finding of an Ozone Transport Region (OTR) study prepared for the Ozone Transport Commission was that "additional VOC reductions when added to strong NOx reductions provide little additional benefit in most areas of the OTR."{5.8.1 [Where ozone drift, up the east coast, from state to state, contributes substantially to ambient ozone concentration is called the Ozone Transport Region (N.VA, DC, MD, PA, DE, NJ, NY, CT, RI, MA, VT, NH, ME)].
A subsequent report to the Ozone Transport Commission on ozone modeling for the New York Airshed found "both ROM and UAM [computer models] have predicted that ozone concentrations in the New York Airshed can be reduced more by NOx [reductions] than VOC reductions".{5.8.2
Because biogenic VOCs lower the effectiveness of VOC-reduction strategies to control generation of ozone, there has been justified concern that current VOC-emission tables may underestimate the proportion of biogenic VOCs (BVOCs) in the total VOC population. Recently, USEPA and NOAA [National Oceanographic and Atmospheric Administration] scientists measured biogenic emissions and generated "An improved model for estimating emissions of volatile organic compounds from forests in the eastern United States".{5.8.3 This new model "yields isoprene (a BVOC) emission rate estimates ...that are 5 to 10 times higher (and total BVOC emission rates that are 3 to 5 times higher) than the Environmental Protection Agency BVOC emission rate model currently used."{5.8.4
A recent EPA-sponsored scientific modeling of ozone-reduction strategies finds that "an earlier understanding of the chemistry of urban ozone indicated that controlling emissions of volatile organic compounds (VOCs), or hydrocarbons, would lower ozone concentrations in the most efficient manner. These controls seemed to work well in the worst urban ozone cases but not so well for the rural and smaller urban areas. Underestimating the importance of naturally occurring VOCs [BVOCs] and the magnitude of anthropogenic VOCs may have overstated the potential for using VOC controls to reduce high ozone concentrations".{5.8.5
The BVOC portion of MDEP's current VOC-emissions inventory is derived from the EPA's biogenic emissions inventory system (BEIS model).{5.9 Thus, current MDEP data on BVOCs exaggerate the effectiveness of VOC-emission-control to lower atmospheric ozone.
I have testified extensively as to the apparent ineffectiveness of MDEP's ozone program{5.10, and MDEP has occasionally hinted that it really does understand the contradiction between its program and established scientific understanding about ozone control.{5.11 With regard to Maine's claim that its VOC-control program will actually enable Maine to meet ozone standards, MDEP Air Bureau Chief Dennis L. Keschl (January 1995) told me,
"We don't know what bringing us into [15% VOC reduction] compliance will do [toward meeting the ozone standard]. Models show we need 75% NOx reductions. Several areas will not be in attainment."5.11.1">{5.11.1
Michaelsen also said that biogenic emissions may be several times greater than predicted and that it is unfortunate the important scientific evaluation is not keeping up with the programs.{5.12
In May 1996, MDEP Air Bureau Chief James Brooks acknowledged that:
MDEP's RFG VOC-reduction program "will provide only limited benefits in controlling ozone".5.12.1">{5.12.1
My own relatively primitive calculations suggest that, in southern Maine where the pollution is worst, the contribution to ozone reduction from VOC reduction is less than 1%.{5.12.2
A recent newspaper story on air pollution and automobile traffic in Maine and New Hampshire quotes New Hampshire Air Resources Division Director Ken Colburn:
Some Maine officials may agree, but they continue CARTEST and MTBE programs that depend on controlling VOCs to reduce ozone.{5.13
The New England Office of the EPA claims that current EPA data show general ozone-reduction in the east that is consistent with automobile-emissions testing and the use of RFG,{5.13.1
From EPA's current air-quality data for the United States,5.13.2">{5.13.2 I have averaged the ozone listings (second-highest daily maximum 1-hour concentrations of ozone from each of 62 eastern U.S. ozone-measuring sites) and plotted in Figure 1 the result for each year from 1986 to 1995.{5.13.3 Thus it can be seen that the EPA data is not a strong argument for a causal relationship between ozone reduction programs and ozone levels.
In fact, the 1988 ozone high and the 1989 low (Figure 1) were described in 1991 by the National Research Council as likely results of "meteorological fluctuations" and furthermore that "the principal measure currently used to assess ozone trends (i.e. 2nd-highest daily maximum 1-hour concentration in a given year) ... is not a reliable measure of progress in reducing ozone over several years for a given area"{5.13.4 and that "over the past two decades, the substantial reductions in ozone concentrations predicted to result from the VOC reductions in major urban centers have not occurred. ...The reasons for this failure are largely unknown."{5.13.5 If the data in Figure 1 were to be considered a "reliable" measure of ozone trends, it seems not much has happened recently (between 1991 and 1995) to suggest an ozone-reduction.
The Clean Air Act Amendments of 1990 (CAAA) cleared the way for the Government to place on the backs of individual automobile owners the responsibility for cleaning up industrial America's dirty air. Those amendments were characterized by U.S. Public Interest Research Group Executive Director Gene Karpinski as a "bad deal for the average citizen, and a bad deal for state and local governments, who would be more vulnerable to economic blackmail by polluting industries".{5.14
A fundamental part of the CAAA was an already scientifically questionable requirement that did not take into account the relevant ozone-producing chemistry. It required that jurisdictions with polluted air implement a plan to reduce man-made VOCs by 15% by November 1996.{5.15 Maine dutifully established such a plan in which automobiles were inspected at central facilities, and owners were required to repair their cars and maintain them to test standards. The program was known both as "CARTEST" and as "I/M" (Inspection and Maintenance).
The testing worked poorly, and overwhelming public anger resulted in petitioning the program to referendum.{6.1 The next attempt to systematically reduce VOCs, and thereby meet the Federal 15% VOC-reduction plan was the introduction of a special gasoline (RFG) to lower automobile VOC emissions.{6.2 This is the program running today in southern Maine.
MDEP administrators offer no rationale of how their 15% Plan could help attain the ozone standard;{6.3 and, as noted above, they now suggest it will not. Even if our gasoline were 100% effective at reducing automobile VOCs, there would likely be, at best, insignificant reduction in Maine's ozone.
On July 18, 1996, EPA Environmental Specialist Robert Judge told me that ozone-reducing benefits in Maine will begin in the year 2000 when a NOx reduction of 6.8% will be required under the Clean Air Act. Judge said he had no information on the effectiveness of Maine's current VOC-reduction program to lower ozone.{6.4 This was the same as his position over a year before when I had asked for specifics on how Maine's program was working. At that time, Judge responded, "The effect on ozone in Maine is best determined by the modeling (UAM) that the MDEP is performing."{6.5 I have since checked with MDEP on this matter and am told that there is essentially no actual atmospheric modeling work being performed at MDEP and that the people who do modeling, with whom MDEP collaborates, are at the Massachusetts Department of Environmental Protection.{6.6
But with the cool summer of 1996 having produced (predictably) less ozone in Maine than in 1995, both Maine and EPA proponents of ozone control through VOC reduction were cautiously optimistic that ozone control was occurring.{6.7 They may have forgotten that ozone levels in the spring of 1996 were fairly high.{6.8
What some VOC-reduction enthusiasts may not know is that whatever improvement in ozone levels RFG might bring would commence within hours of reducing VOCs. It's now well over 2 years since the arrival of RFG here in January 1995, and the closest thing to an RFG program appraisal from State officials is, "Well, the jury's still out on RFG". Unfortunately, taxpayers who suffered from bad air in 1995 may not care how the "jury" analyzes that year's air pollution.{6.9 The air still got bad.
Because general features of the raw ozone data may be obscured by data- processing and information presentation, it is difficult for the layman to assess ozone trends in Maine. Publishing of MDEP ozone data is over a year behind; I obtained the 1995 Air Quality Report in March 1997. While members of the MDEP staff are very helpful in providing preliminary up-to-date data, the basic policy on handling and publishing of ozone data at MDEP may need review.
For instance, the news article mentioned above{6.10 cited 1995 and 1994 ozone data as suggestive that ozone wasn't so much worse in '95 than in '94. A look at the data suggests a different story. Sometimes ozone pollution is presented in terms of the number of days in which ozone exceeds the Federal standard of 120 parts per billion (ppb); but for assessing danger to public health, it would make sense to examine the number of hours ozone concentrations exceed the more prudent Maine Advisory Level of 81 ppb.{6.11 Figure 2 displays the relationships of 1995 to 1994 ozone exceedance-hours at six measurement sites in Maine. Even EPA's Region-1 chief John DeVillars cited New England air as being more unhealthy in 1995 than in 1994.6.11.1">{6.11.1 MTBE-RFG was in use in Maine throughout almost all of 1995.
MDEP is in a bind. It is managing an expensive ozone-reduction program that is at best ineffective, and at worst a threat to public health, a situation that has dictated an emphasis on public relations and a flashy MDEP computer-generated video presentation to overcome the program's flawed scientific basis. Progress in Maine's ozone reduction program is "tracked" in the Annual MDEP Air Quality Reports which carry tables of measurement data, but which present little in the way of data explanation or of ozone-reduction assessment.
Page 24 of the current [1995] MDEP Air Quality Report carries tables of second-highest annual ozone measurements that exceed the Maine health advisory level of 81 ppb; these measurements were taken at five sites in Maine. Page 25 carries more tables of percentile-arranged ozone concentrations, from the same sites, and presumably derived from the same raw data as are the tables on page 24.
One would think that two pages of such basic ozone data (and many pages of tables that follow) should merit some scientific discussion that the taxpaying public (which has paid for the data) could contemplate. There is none. For example, if one wishes to know the degree of ozone-reduction progress that followed the introduction of MTBE-RFG into Maine in early 1995, he can peruse tables such as on pages 24 and 25 and discover that the most recent figures on page 24 show ozone to have somewhat increased since 1994, and that the corresponding figures on page 25 show it to have somewhat decreased. This discovery may seem of limited value to some people, but it allows MDEP the strategic flexibility to either:
(a) claim credit for ozone-reduction (page 25), or
(b) seek funding toward achieving ozone-reduction (page 24).
Negative effects of ozone on human beings have been measured at concentrations down to 20 ppb.{6.12
This section compiles some recent and current opinion and study on: (1) the effectiveness of gasoline oxygenate MTBE in reducing emissions from automobile engines, and (2) the effects of MTBE on the environment.
Gasoline manufactured to reduce certain automobile emissions is called reformulated gasoline (RFG). The RFG sold in Maine is said to differ from conventional (regular) gasoline in mainly three respects. Benzene makes up about 1% of RFG, and about 1.5% of regular gasoline; the Reid vapor pressure (RVP) of RFG is lower than that of regular gas;{7.1 and an oxygenate is added.
Oxygenates are chemicals containing oxygen that, when added to a fuel, supply extra oxygen to the combustion process so that fewer uncombusted hydrocarbons (HCs or VOCs) and less carbon monoxide (CO) are supposed to remain among the exhaust products. Regular gasoline, to which only an oxygenate has been added, is called oxygenated gasoline. Federal law defines reformulated gasoline as containing an oxygenate.{7.2 The oxygenate used in Maine's RFG gasoline is called MTBE (methyl tertiary butyl ether).{7.3 Listed as a hazardous air pollutant in the Clean Air Act,{7.4 "MTBE is now the second most made chemical in the world."{7.4.1 In the United States, it is the primary oxygenate in 84% of oxygenated gasoline.{7.4.2
"Changes [other than the above -- oxygenates, benzene, and vapor pressure] are due primarily to dilution from oxygenates [MTBE in Maine]".{7.5 Thus the highly proclaimed reductions of aromatics (toluene, xylene, naphthalene) in RFG may be governed primarily by the amount of the oxygenate dilutant.
It is not easy to determine the gasoline formulations actually used in Maine. In July, 1996, I asked our regional EPA representative Robert Judge what's in Maine's gasoline. "Not sure. Ask Ron Severance [at MDEP]", he answered. I asked the MDEP, the Maine Oil Dealers' Association, the Maine Petroleum Association, the Natural Resources Council of Maine, the American Lung Association of Maine, and a member of Governor King's Task Force on RFG (Task Force). Nobody had the information at hand. Eventually, EPA's Bob Judge was able to provide me with EPA measurements of Portland, Maine fuels that ran approximately 11% MTBE.
Oxygen is about 18%, by weight, of MTBE. So, an 11% MTBE gasoline contains about 2% oxygen.
MDEP says it does not monitor the chemical ingredients of gasoline; officials assume that Maine RFG contains about 11% MTBE.{7.6 and that benzene is reduced from the approximately 1.5% in Maine's regular gasoline to about 1% in Maine's RFG.
Upon request, the MDEP staff provides an industry-generated gasoline specification (Material Safety Data Sheet) that bears a range of constituent concentrations such as 0-15% MTBE, 10-1170 parts per million (ppm) sulphur, and 0.1-5.18% benzene. Thus, actual composition of Maine gasolines cannot be determined from industry specifications.{7.8 Except in the ozone non- attainment areas, Maine does not know where oxygenated fuel is sold. "We have a feeling it [11% MTBE formulation] is being used in other parts of the State, but we don't regulate that", says MDEP's Scott Wilson7.9">{7.9
An unfortunate aspect of this general lack of information is that even the Governor's Task Force, appointed to study the health effects of RFG, did not know (except for MTBE) the actual differences between various RFGs and regular gasolines used for years in Maine.
Following the introduction of MTBE as a gasoline additive in the United States, testing of gasolines for combustion-emission products along with measurements of ambient air pollution and water pollution have taken place. This sub-section reviews some of the discoveries:
A 1992 industry report on automobile engine emissions found NOx emission levels to be higher with oxygenated, than with regular, gasoline.{8.1
Another 1992 industry report examined the effect of oxygenates on automotive emissions (primarily CO) at sea level and at 5,000 feet altitude.{8.1.1 While at high altitude some measurements showed that oxygenates lowered CO emissions, these reductions for most fuel-injected cars were small (somewhat higher for carbureted cars); and at low altitudes some measurements showed even less, or no, effect from oxygenates. More or less the same was true for the effect of oxygenates on hydrocarbon (HC -- VOC) emissions: no changes for most measurements at sea level, but with more measurements showing decreases at 5,000 feet altitude. Many measurements found NOx emission to increase with the use of oxygenates.
A 1993 related study found that "increasing MTBE [oxygenate] in gasoline raised NOx [emissions] in low aromatic fuels"; and that lowering gasoline sulphur lowered NOx [emissions]".{8.2
A 1994 EPA report found, "with MTBE-reformulated gasoline, benzene and butadiene emissions decrease, whereas formaldehyde and MTBE emissions increase, all within the context of a net decrease in hydrocarbons."{8.3
A 1995 study of two gasolines blended for use under strict California air- quality requirements{8.4 found no statistically significant differences in automotive emissions between an MTBE RFG and a non-MTBE RFG (RFG with no MTBE added) with regard to the emission of hydrocarbons, non-methane hydrocarbons, CO, NOx, and total toxics emissions. The only statistically significant difference found was that the MTBE RFG produced more formaldehyde emission than did the non-MTBE formulation. Characteristic of both of these gasolines was low sulphur content and low T90.{8.5
Cook et al (EPA) argue that atmospheric CO-reduction results from use of oxygenated fuel.{8.5.1 CO measurements from 300 sites in the United States are presented to show an average of 9% reduction of CO in 1992 in locations where oxygenated fuel is now in use, compared to places where it still isn't.
A 1994-1995 study by the State of Utah Department of Environmental Quality found that, during the months of December('94) and January('95) when 2.7% oxygen-content ethanol- and/or MTBE-oxygenated fuel was used in Utah County, the air in Utah County and neighboring Salt Lake County was found to carry 300% to 1800% more formaldehyde, 470% to 860% more acetaldehyde, 50% to 520% more CO, and 30% to 110% more NOx -- than during February('95) when no oxygenated fuel was used in either county.{8.5.2 Oxygenated fuel is part of Utah County's wintertime carbon-monoxide (CO) control strategy.
A 1996 study of ambient air in the Caldecott tunnel between Berkeley and Orinda, California finds VOC and CO emissions-per-mile are lowered, formaldehyde emissions raised, and NOx emission raised slightly by the establishment of the oxygenated fuels program.{8.6
A 1996 Federal Final-Rule modification relaxes a previously required consideration of the potential negative impact of oxygenated fuels. The previous rule had stated that, when considering an oxygen-content increase to the 2.7% maximum in a reformulated fuel, it must first be determined that "no adverse NOx [emission] impacts can be shown".{8.7 For instance, in California, the required oxygen content of gasoline had been reduced from the EPA-mandated maximum of 2.7% to "1.8 - 2.2% by weight because of concerns of possible increased NOx emissions".{8.8 Under the new rule, the maximum oxygen content has been raised to 3.2%.
The 1997 Final Report of the Auto/Oil Air Quality Improvement Research Program (AQIRP, Sustaining Members: the American Petroleum Institute, Society of Automotive Engineers, and the U.S. Council for Automotive Research) reviewed and summarized the findings of a series of studies started in 1989.{8.8.1 Among the findings are:
Commenting on the AQIRP Report, an Oil and Gas Journal editorial said:
The National Research Council suggests that oxygenated fuels may not contribute as much to the reduction of CO as predicted by EPA computer- modeling.{8.9 Larry G. Anderson and others{8.10 measured CO concentrations in and around Denver, Colorado and found "no significant effects of using oxygenated fuels on the ambient concentrations of CO".{8.11 "Our analysis suggests that at sites with lower concentrations at the outset, the program [oxygenated fuels] has had an impact on lowering those concentrations, although not by as much as MOBILE and AIRSHED [computer models] predicted."
"Our [analyses] ... show a decrease in CO prior to oxygenated fuel use, supporting the hypothesis that changes in the vehicle fleet composition have had a more significant impact on reducing CO pollution than the oxygenated fuel program."{8.12 "...our analysis of ambient CO data along Colorado's Front Range has found no significant effect of using oxygenated fuels on the concentration of CO during recent winters".{8.13
In April, 1997, at a CRC On-Road Vehicle Emissions Workshop, Anderson et al. reported, "We seem to be reaching a consensus that the benefits of oxygenated fuels use [for CO reduction] are typically in the range of 5-15%, not the 20-30% predicted by the early emissions modeling approach".{8.13.1
Anderson et al. have found: "Emissions test data suggests that both formaldehyde and nitrogen oxides (NOx) emissions increase when methyl tertiary butyl ether (MTBE) blended fuels are used".{8.14 As for NOx automobile emissions, measurements conducted by the Colorado Department of Health find that when 11% MTBE is added, NOx is decreased 4.5% in cars without catalytic converters, and increased 4% in those having converters; emitted formaldehyde was decreased 17% in the non-catalytic-converter cars, but increased 23% in catalytic cars and increased 76% for closed-loop emission-control cars (latest models).{8.15 Regarding ambient NOx concentrations, "the trend analysis has shown no significant effect of using oxygenated fuels".{8.16 "The fuel reformulation mandated by the oxyfuels program induces higher emissions of formaldehyde and acetaldehyde, both probable human carcinogens".{8.17
The Collegium Ramazzini{8.17.1 has found:
On January 29, 1996, gasoline was discovered emanating from the ground at British Petroleum's (BP) fuel storage and transfer center #10161 (59 Main Street, South Portland, Maine) a block from the Fore River.{8.18 An early news story reported 17,000 gallons of gasoline to have leaked from a pipe with some spillover into the River.{8.19 The MDEP estimated the loss at 53,000 gallons, perhaps more, perhaps less; and the estimate of total recovered amount may have increased, or decreased, with time.{8.20 A suspected second gasoline leak of undetermined amount, about 1000 feet from the first leak, was investigated by MDEP.{8.21 As of December 1, 1996, there was no MDEP information available as to the formulations of the gasoline that leaked, nor had the commencement date of either leak been determined. By February 1997, MDEP had determined that the first leak was MTBE gasoline.
After discovery of these gasoline leaks, measurements of ground water at the spill site showed MTBE contamination far higher than for other pollutants -- as high as 4.1 million ppb. The October 17, 1996 monitoring report showed dissolved ground water pollution from six test wells to be between 23,000 ppb and 940,000 ppb of MTBE. In contrast, dissolved benzene pollution in the same wells ran between 990 and 8,700 ppb. Water from the test wells was treated in an on-site decontamination system; the effluent therefrom, containing 62,000 ppb of MTBE, was released into Rolling Mills Pond, which in turn emptied into the Fore River.{8.22
The Maine health advisory level for MTBE in drinking water is 50 ppb.{8.23 Treated effluent water (62,000 ppb of MTBE), flowing into the ground from the 1996 BP gasoline-spill cleanup operation, contained 1,240 times this level. Nine months after discovery of the spill, the concentration of MTBE in untreated test-well ground water had been running (October 1996) up to 18,800 times Maine's health advisory level.
In the first of a comprehensive two-part series on MTBE, William Carlsen of the San Francisco Chronicle has explained how
Garrett et al (MDEP, and University of Maine, 1986){8.24 find that MTBE in gasoline "may increase the sum total of all dissolved gasoline components in ground water", that water contaminated with MTBE is difficult to remediate, and that activated-carbon filtration of MTBE-contaminated water is not cost- effective. For these reasons, engineers at the BP gasoline-spill site in South Portland, at least for the time being, rejected using carbon filters for removing MTBE from contaminated water and air.{8.25
The United States Geological Survey (USGS) has found MTBE in 79% of shallow wells tested in Denver Colorado; in 37% of those tested in Connecticut, Massachusetts, and Vermont; in 25% of those tested in Chester County, Pennsylvania; and in 100% of those tested in northern New Jersey. Three percent of the tests showed MTBE to exceed the lower level of the EPA- recommended health advisory for MTBE. MTBE was the second most commonly detected VOC in urban wells -- chloroform being detected 4% more often. The concentrations of MTBE ranged from the minimum detectable level of .3 ppb to a high of 31,000 ppb. In shallow groundwater wells in the lower Susquehanna River Basin in Pennsylvania and Maryland, and in the Connecticut, Housatonic, and Thames River Basins, MTBE was the most commonly detected VOC.{8.26
In groundwater, MTBE has been found to degrade very little over a period of 16 months; it's fate over longer periods is uncertain.{8.27
The USGS, also, finds that "MTBE [in water] does not biodegrade easily. ... If a research investigation determines that a compound does not degrade, a half-life is not reported and the compound is simply classified as "recalcitrant". MTBE is generally reported as recalcitrant, and there are no widely accepted estimates of its half-life. ... Yeh and Novak (1995) reported that there was no degradation of MTBE in an aerobic laboratory study after more than 100 days of incubation."{8.28
... "Despite the resistance of MTBE to indigenous bacteria, biotreatment methods might be developed. Recent research has demonstrated that bacterial populations and certain pure bacterial strains, when isolated from biotreated sludges and other sources, have the ability to use MTBE as a sole carbon source (Salanitro and others, 1994; Mo and others, 1995)."{8.29
With respect to public health, the USGS has advice that should be taken seriously:
"Defining the source of MTBE in shallow ground water is essential to prevent further contamination, and to protect other vulnerable aquifers in the United States from contamination by MTBE or similar compounds. ...
"In order to determine if MTBE concentrations are likely to rise above current levels and potentially rise to levels that pose a health threat, it is necessary to understand three things about the compound: (1) the pathways by which it enters the ground water, (2) the processes by which it is transported in ground water, and (3) the rates at which it degrades. Only when all three of these issues are reasonably well understood can meaningful projections be made for the potential for MTBE reaching dangerous levels over long periods of use".{8.30
MDEP says most reported cases of water pollution in Maine involve gasoline spills; in almost all of these cases MTBE is found; in some cases, it is the only gasoline constituent measured. In Lisbon Falls, Maine, measurements of water in a test well situated less than 10 feet from a town drinking-water well found MTBE to be present at 2.8 ppb. Six ppb of MTBE has been measured in a town drinking-water well in the neighboring town of Lisbon.{8.31
But researchers have been somewhat disconcerted to also find MTBE in what they call ambient groundwater -- groundwater not near any known or suspected sources of pollution. A Geological Survey hydrologist in Trenton, NJ, Eric Everson, says the northern New Jersey sites, where MTBE was found in groundwater, were so far apart that it was "highly improbable" that a spill could have caused the contamination. Hydrologist and Chief of the National VOC Synthesis Project, John Zogorski, says that MTBE automobile emissions in the air may return to the groundwater in droplets of rain. Zogorski also notes that researchers did not expect to see MTBE in groundwater so soon. "It wasn't like we were out there trying to find it; it just showed up. The fact that MTBE showed up in roughly five years was surprising. Many environmental contaminants take longer than that."{8.32
Zogorski also wants to see research on the presence of MTBE in rivers and streams. He said he doesn't expect to find much MTBE there, but that it is a concern because much of this water is used for drinking and because researchers don't know yet how MTBE affects aquatic life.{8.33
American Waterworks Association chemist John DeBoer says:
"the chemical [MTBE] is more ubiquitous, and perhaps more long lasting, in the environment than I would have anticipated. It has the potential, then, to be a much more serious contaminant, both for drinking water as well as for other uses."{8.34
"In a bitter irony for California's environment, the year-old reformulated gasoline credited for sharply reducing smog is polluting drinking-water reservoirs from Riverside to Redding with a long-lived contaminant that resists ordinary filtration. ... samples from Shasta Lake measured MTBE as high as 88 ppb near the drinking water intake..."{8.35
Officials at ARCO, a primary manufacturer of MTBE, say there should be little concern given the levels of MTBE that have shown up in water samples so far.{8.36
MTBE contamination has forced discontinuance of seven of the eleven municipal wells in Santa Monica, California. One Santa Monica water-supply well, showing only 14 ppb of MTBE when first tested, rose later to 490 ppb. The City of Santa Monica is suing for damages for the MTBE pollution of its wells. John Froines, Chairman of UCLA's (University of California at Los Angeles) Department of Environmental Health Sciences, said:
"it is a scandal that we have gotten to this point, with millions of pounds of this stuff [MTBE] being manufactured and so little known about its hazards".
"Froines faulted the USEPA for failing to assess the results of Italian research on laboratory animals, published in 1995, which made the strongest link so far between MTBE in drinking water and cancer."{8.37
"EPA officials in California and Washington declined this week to be interviewed about MTBE unless their names were withheld from print -- an unusual condition for the agency. On that basis, several EPA officials acknowledged that the agency has an incomplete knowledge of MTBE's health effects but said there are plans to review the Italian research by Cesari [sic] Maltoni, head of the Bologna Institute of Oncology. In the meantime, according to California officials, the EPA has issued a "health advisory" recommending a maximum limit of 70 ppb for MTBE in drinking water."{8.37.1 [The EPA did consider, but did not actually issue a 70 ppb advisory; but on December 8, 1997, the EPA officially lowered the maximum level of its MTBE health advisory from 200 ppb to 40 ppb. (See note U2.39.8.)]
This is an 80% reduction of the EPA advisory maximum for MTBE, but it is still 750% above the 5 ppb maximum recommended by Myron Mehlman.{8.37.2
In the Santa Clara Valley Water District (California), in 217 of 285 MTBE groundwater monitoring cases, MTBE contamination measured from 5 to 260,000 ppb.{8.37.3 Although MTBE has not yet been found in Santa Clara drinking water, Santa Clara underground-fuel-tank program supervisor James Crowley says:
"MTBE is one of the biggest threats we've ever faced".{8.37.4
"You've got a hell of a problem here which should have been anticipated but was not". [California State Senator Tom Hayden.{8.37.5]
MTBE has polluted town wells supplying water to the Village of Liberty, New York.{8.38
In 1995, 13 homes in Orange Lake, New York were equipped with devices to filter drinking water because wells showed levels of MTBE up to 5,800 ppb from an unknown source. There are no gasoline stations nearby.{8.39 A New York State Department of Health Study lists sites at which remediation of MTBE in drinking water has been employed. This study was prepared under cooperative agreement with the Agency for Toxic Substances and Disease Registry, U.S. Public Health Service.{8.40
Tests of private wells in Tiverton, Rhode Island have found drinking water contaminated with up to 2,850 ppb of MTBE -- over 70 times the State's health advisory level of 40 ppb.
Rhode Island's Drinking Water Quality chief, Jane Swallow, says, "MTBE doesn't have acute (health) effects. It's the kind of contaminant we're all exposed to pretty much every day. ... The health effects are still being assessed. At high exposure it could cause headaches, nausea, a cough. There is some disagreement about other problems it can cause". Swallow said the effects of drinking the substance are less clear, but that the "contaminated water is considered safe for bathing as long as an exhaust fan is used during the shower or bath".
Tiverton resident Evelyn Gouveia, whose well has tested positive for MTBE, said, "They say it's safe to use for washing and bathing, but who wants to use water that smells like gasoline?" "You can smell it", said Rita Pires, another resident. Other residents complained of skin rashes they say are caused by contact with the water, smelling oil in their houses or even seeing an oily sheen.{8.41
On Castle Hayne Road in Wilmington, North Carolina, MTBE and benzene have penetrated downward through one aquifer and into another under a neighborhood of residential dwellings which obtain drinking water from wells that draw from both aquifers. The top of the deeper aquifer is about 50 feet below ground level. Benzene and MTBE concentrations at the bottom of the upper aquifer have been measured at 470 and 1600 ppb respectively. During 1995, the North Carolina Department of Health and Natural Resources along with the Conoco Oil Company have provided bottled water and carbon water-filters to residences.{8.42
On August 25, 1997, a federal jury ruled that the Conoco Company acted willfully, negligently, and fraudulently and contaminated the well water of 178 residents on Castle Hayne Road. The jury awarded $9.5 million to the residents to be used for continued medical monitoring and health care.{8.42.1 In the wake of this judgment, it was reported that:
"top management of a major U.S. gasoline refiner has been warned by its technical personnel that the problems of MTBE water contamination are so bad that the company's total liability over the next 20 years could approach $500 million".{8.42.2
A spill of MTBE gasoline at the Somersworth, New Hampshire Cumberland Farms store has contaminated the water, ground, and air to the extent that Peggy McLin experiences grogginess from being in her home.{8.43
Oxygenate MTBE is listed as a Hazardous Air Pollutant by the Clean Air Act. Pollutants listed therein "present ... a threat of adverse human health effects (including but not limited to, substances which are known to be, or may reasonably be anticipated to be, carcinogenic, mutagenic, teratogenic, neurotoxic, which cause reproductive dysfunction, or which are acutely or chronically toxic)".{8.44
Following complaints of health effects in Anchorage and Fairbanks, Alaska, the use of MTBE-oxygenated fuel in Fairbanks was suspended by the Alaska State Government in December 1992. The Alaska Department of Health recommended that use of MTBE- oxygenated fuel be suspended also in Anchorage.{8.44.1 Since March, 1993, MTBE-oxygenated fuel has not been used there.
In July 1993 the Alaska Health Department and the Department of Environmental Conservation expressed concern that EPA protocols for MTBE health studies "do not answer the ultimate question of whether MTBE poses health risks or whether there is a net health benefit in using MTBE to lower CO emissions in Alaska".{8.44.2
In August 1993, the Alaska Public Health Association, the State Medical Association, and the Anchorage Board of the American Cancer Society passed resolutions asking for discontinuance of MTBE-oxygenated fuel until such time as scientific studies establish that exposure to MTBE does not create an unreasonable risk of cancer or other dangers to human health.{8.44.3
Concerns over health threats from MTBE led North Carolina to suspend use of MTBE-oxygenated fuel in 1995.{8.44.4
In 1994, The American Medical Association adopted a resolution urging "a moratorium on the use of MTBE-blended fuels (in Alaska) until such time that scientific studies show that MTBE-blended fuels are not harmful to health..."{8.45
The American Public Health Association called upon the U.S. Congress "to take appropriate action to ensure that adequate scientific studies are funded and conducted on oxygenated fuels including studies of the potential toxicity of MTBE ..."{8.46
"The Lone Star (Texas) Chapter of the Sierra Club strongly opposes all use of reformulated gasoline with MTBE, primarily for health reasons. The untold toxic story about the petroleum-based oxygenate suggests that MTBE may be more harmful than ozone." Neil J. Carman, the Club's Clean Air Director says, "MTBE appears to be another perfect example of a synthetic organic chemical being developed and marketed without having been comprehensively or even adequately tested as to all known adverse health effects on human beings."{8.46.1
The USEPA finds, "There are no studies on the health effects in humans from long-term or lifetime exposure to MTBE in drinking water or air".{8.47
MDEP claims: "Very little is known about air toxics in Maine and the concentrations to which people are being exposed; an enhanced inventory is necessary to define all sources of hazardous air pollutants. ...Five monitoring sites targeting hazardous air pollutants were established in November and December 1995 in the greater Portland area."{8.48 The 1995 MDEP Air Quality Report lists 36 hazardous air-pollutants to have been monitored in 1996 and 1997 at these sites; though 11% MTBE gasoline has been in use in Maine for about two years, neither MTBE nor formaldehyde is on this MDEP list.{8.49 Said Maine State Toxicologist Andrew E. Smith: "We are not aware of any Maine ambient air monitoring data for MTBE."{8.50
In the highly charged atmosphere of automobile-emissions discourse here in Maine, it's often difficult to sort fact from argument. I decided to start from the beginning and find out what EPA engineers have to say about comparative emission characteristics of gasolines and how those numbers are derived.
At the recommendation of Robert Judge, I called David Korotney, a chemical and mechanical engineer with the EPA in Ann Arbor, Michigan. Korotney reviewed for me the procedure by which the EPA derives emission characteristics of combusted fuels, through the use of EPA's Complex Model. This computer model was originally derived from laboratory emissions-testing of fuels having various formulations. Into this model is entered a basic formulation, and the model predicts emission characteristics of that fuel.
Because some claim that oxygenated gasoline lowers NOx levels, I asked Korotney about 1992 test data{9.1 that show increasing NOx emission with increasing oxygenate concentration; and the 1995 test data{9.2 that find no statistically significant lowering of NOx or CO from the use of oxygenates. He explained that some differences between test results and computer predictions are because the Clean Air Act (CAA) provides leeway to set the ratio of high- to low-mileage automobiles fed into the Complex Model. He said that whether NOx emissions increase or decrease with addition of oxygenates can depend on the mileage of the vehicle. He said it was not unreasonable to raise the question whether a given reformulated gasoline would pass the "zero increase" NOx test{9.3 required by the CAA.
I asked about emissions of the five statutory toxics (benzene, 1,3 butadiene, polycyclic organic matter, acetaldehyde, and formaldehyde){9.4 and the suitability of the word "aggregate" (of toxic emissions) which is defined as the sum-by-weight of toxic emissions from a motor vehicle. He said my question involves consideration of the comparative potency of individual toxics, and that within the EPA there are no potency ratings that are considered really trustworthy (formaldehyde, for instance, as an individual toxic that has some level of "potency" relative to, say, benzene).
We discussed the above-referenced 1995 industry report comparing the properties of different formulations of gasoline.{9.5 He was familiar with the formulations and discussed the low sulphur and the low Reid-vapor- pressures (RVP) of two of the gasolines, noting that they were in line with Phase-II California fuel formulations. ("Phase-II" fuel formulations address environmental regulation goals for the Year 2000.{9.6)
For these two Phase-II low-sulphur/low RVP gasolines, a major difference was that one of the gasolines contained 11% MTBE, and the other had none. Korotney provided me with Complex Model predictions for the combustion emissions for these fuels. The model predicts both fuels would perform better than Maine's MTBE-RFG with respect to emissions of VOCs, benzene, total toxics, CO and NOx. Furthermore, the non-MTBE Phase-II fuel also performed better than Maine RFG on formaldehyde, and performed better than the Phase-II MTBE fuel regarding formaldehyde and NOx reduction. The MTBE formulations increase formaldehyde emission over that from conventional gasoline.{9.7
Regarding octane ratings of gasoline, I asked Korotney about the effects of adjusting the amounts of aromatics or oxygenates. Taking Maine's RFG gasoline as an example, he estimated that a 1/2% reduction in benzene might reduce gasoline octane approximately 1/10 point (insignificant), and that an 11% increase in MTBE would increase octane about 2 points. [Thus benzene and MTBE have approximately equivalent octane-enhancing power.]
In this section are my comments on six U.S. Government studies of oxygenated fuels and on a Colorado Department of Public Health and Environment (CDPH&E) automobile emissions report: three CDC (Centers for Disease Control and Prevention) studies{9.7.1, an EPA (U.S. Environmental Protection Agency) report{9.8, an OSTP (Office of Science and Technology Policy) draft report{9.9, an NRC (National Research Council) report{9.10, and the CDPH&E report{9.11. The NRC Report reviews the OSTP Draft, part of which is a study by the Health Effects Institute.{9.11.1 The final edition of the OSTP study was published in June 1997.{9.12
The 1992-1993 CDC Study in Fairbanks, Alaska was conducted jointly with the Alaska Department of Health and Social Services. It established a correlation between MTBE in workplace air and MTBE concentrations in workers' blood. Key health complaints: "headache, eye irritation, burning of the nose and throat, nausea or vomiting, cough, dizziness, or a sensation of spaciness or disorientation" are reported and are related to MTBE blood concentrations, but the authors found the relationship to be "not statistically significant", and that because of small sample size, "we may not have had adequate power to detect relationships if they were present".
When 15% MTBE was in use in Alaska, measured workplace air exposure-levels ran from 6 to 800 ppb with a median level of 100 ppb. The key health complaints dropped significantly when use of the 15% MTBE winter gasoline program was abandoned and replaced with 0.4% MTBE regular gasoline and 5% MTBE premium gasoline.{9.12.1
The 1993 CDC Study in Stamford, Connecticut was conducted jointly with the State of Connecticut and the City of Stamford. The 1993 CDC Study in Albany New York was conducted jointly with the New York State Department of Health. These two studies were similar to that done in Alaska; but they were also different in that Stamford used 15% MTBE for control of carbon monoxide, whereas the median level of MTBE in samples of Albany's gasoline was less than 2% (used for octane enhancement only).
As in Alaska, MTBE blood levels were correlated with air exposure-levels in both Stamford and Albany; the levels were higher in Stamford than in Albany. In Stamford, the air exposure-levels ran from 1 ppb to 12,040 ppb, with the median value 150 ppb. In Albany, the measured MTBE air exposure-levels ran from nondetectable (less than 5 ppb) to 11 ppb; the median MTBE sample level was "nondetectable".
In both Stamford and Albany, Alaska-type health symptoms were reported. In Stamford the symptoms were "significantly" correlated with MTBE blood levels. In Albany there was a slight but not significant increase in health complaints with high MTBE-exposure, compared to lower-exposure, groups. The Stamford Study concluded that the "possible relationship between blood MTBE levels and health symptoms needs further clarification".{9.12.2
The 1996 EPA Report "Oxyfuels Information Needs", poses the question "What is the net benefit or risk to the environment and public health resulting from a change from conventional gasoline to oxyfuels?" The answers: "Although the objectives of the oxygenated gasoline and reformulated gasoline programs are quite explicit in seeking to reduce CO, ozone, and air toxic pollutants, a thorough examination of the successes or failures of the oxyfuel programs is needed to answer the question just posed" (p.20). "Ambient monitoring is needed to ascertain which toxic and criteria air-pollutants are increased or decreased, and the extent of such changes, as a function of a change from conventional gasolines to oxyfuels. Empirical information of this type is essential to validating the effectiveness of the oxyfuel programs" (p.21).
After asserting that "the effects of MTBE-gasoline mixtures have not been investigated under controlled inhalation conditions" (p.23), the EPA concludes: "The available information on conventional gasolines and neat oxygenates (viz., MTBE) is not sufficient to support quantitative, comparative assessments of the health and environmental benefits and risks of oxyfuels in relation to conventional fuels" (p.28).
Though the EPA supports use of RFG,{9.13 it seems not to have put its final imprimatur on oxygenated fuels. [The above page-number references are to pages in the 1996 EPA Report.]
Prepared under the direction of the United States Office of Science and Technology Policy, the 1996 OSTP Draft Report, "Interagency Assessment of Potential Health Risks Associated with Oxygenated Gasoline", concluded that "chronic non-cancer health effects would not likely occur at an environmental or occupational exposure to MTBE." Nevertheless, the OSTP Report found:
[The page numbers for items 1 through 6 above are taken from the Executive Summary of the Draft OSTP Report that is included as pages 151-160 of the NRC Report (see note 9.9.]
The National Research Council established a Committee to review the OSTP Draft Report. The Committee's product is the 1996 NRC Report. It breaks no new scientific ground, but does provide insight into what U.S. Government scientific advisers are thinking. It concluded that existing information on MTBE and oxygenated fuels does not show oxygenated fuels likely to pose a substantial health risk -- but that until existing information is supplemented with more studies, "no definitive statements can be made regarding these health-risk issues." The findings:
The National Research Council press release announcing this 1996 NRC Report was headlined, "AIR QUALITY AND HEALTH EFFECTS OF WINTER GASOLINE ADDITIVES NEED FURTHER STUDY".{10.1 [The page-number references in items (a) through (i) above are NRC-Report page numbers.]
An earlier (1991) NRC study had found that "despite the major regulatory and pollution-control programs of the past 20 years, efforts to attain the National Ambient Air Quality Standard for ozone largely have failed".{10.2
In response to the 1996 NRC Report which recommended further specific studies of oxyfuels,{11.1, the Colorado Department of Public Health and Environment Report compiled emission measurements from about 47,000 1982 and newer motor vehicles (cars and light trucks) that failed the metropolitan Denver emissions test.{11.2 The study covered the period of July 1995 through June 1996; oxygenated fuel was in use there for the months of November through February. Because this study involved only one set of vehicles (no controls), there was no way to distinguish with certainty fuel-specific emissions effects from those perhaps caused by seasonal or temperature changes. The study credited oxygenated gasoline with substantial reduction of CO and HCs. It accomplished this by citing reductions between mid-summer (no oxygenate) and mid-winter (oxygenate) for CO and HC emissions of 28% and 13% respectively.
The differences between measured emissions for the month prior to and the month following fuel changeover from conventional to oxygenated fuel and vice versa (October/November and February/March) are likely (but not certain) to be less influenced by seasonal effects than are the differences between mid- summer and mid-winter measurements. At these fuel changeover times, CO emissions were observed to be 7 to 9% lower, and HCs 0 to 3% lower -- with oxygenated fuel.
Not initially provided to the news media, or to myself, were the NOx measurements that were part of the Study. These figures, at fuel changeover times, show NOx emissions to increase between 7 and 21% with the use of oxygenated fuel, with a 25% NOx increase from mid summer to mid winter.{11.3
The Final Edition (1997) of the OSTP Report{11.3.1 has some valuable observations:
This Final OSTP Report carries a letter of introduction from John Gibbons, Assistant to the President for Science and Technology. That "Dear Colleague" letter gives a hint of the current level of confidence enjoyed by fuel oxygenates among federal officials who let MTBE out of the laboratory before it was adequately tested:
"... Data are insufficient to complete a thorough risk assessment of the oxygenated fuels program; thus several critical issues are currently being researched by several Federal agencies. These agencies are developing plans to expand monitoring and research efforts on occurrence of oxygenates in drinking water, the extent of human exposure to oxygenates, probable effects of human exposures, site remediation, and impacts on aquatic life."{11.3.2 - John H. Gibbons
An EPA chemical consultant has told me, "I don't think oxygenates are required in Maine. My personal opinion is that there should have been no oxygenate requirement. Oxygenates were instituted to benefit special interests. Maine could have designed its own gasoline program,{11.4 its own fuel, but that would have taken more work than to accept alternatives from an already prepared list. The United States Secretary of Environmental Protection objected to oxygenates, but dropped her objection because it became obvious that it would be politically difficult."
Bad science is just part of the problem; bad politics is most of it.
It is important to recognize that with respect to cleaning up the air, arguments about industry's favorite gasoline formulations are somewhat academic. The lives of people who suffer from ozone may not be noticeably improved unless we lower ozone 50% or so.
The lowering of ozone concentration by any of Maine's current VOC-reduction strategies might be 5% at best, but probably less than 1%.{11.5 The reason the Boston Office of the EPA is not willing to predict efficacy for Maine's VOC-reduction therapy on ozone is because it has no scientific basis to do so. EPA also probably knows that the difference in ozone-reduction effectiveness between Maine's conventional gasoline and a better fuel (California- formulated, low sulphur) is insignificant. New England EPA Director John DeVillars has told me that my estimates of the effectiveness of Maine's RFG program are "about right".{11.6
And the Ozone Transport Assessment Group (OTAG) has "voted 32-5 for a package of recommendations to the EPA, including for the first time [underline mine] a proposed ceiling on emissions of nitrogen oxide (NOx)."{12.1 [OTAG is an association of states (of which Maine is a member) that deliberates on drifting (transportation of) air pollution.]
As I have noted, the ineffectiveness of VOC-reduction strategy in Maine has been widely known for some time. A handout, provided to Governor King's RFG- stakeholders advisory group, presented graphs (Figure 3) that show the predicted impact of "fuel options" on both VOC and NOx automobile emissions: namely that, nationwide, a VOC-reduction strategy won't keep up with CAA requirements after 1999; and, most important, NOx, which should be reduced in Maine (in order to reduce ozone) will not be lowered by the oxygenated gasoline used in Maine (Federal RFG).{12.2 RFG gasoline may be able to lower NOx if it is a California-like formula -- low sulphur fuel, but without MTBE. To maximize NOx reduction, oxygenate may have to be abandoned. In any case, a California-like formula will produce less NOx emission than Maine's oxygenated fuel.
The COMMITTEE should bear in mind that much of the reduction of pollutants claimed by oxygenate and RFG advocates are what one would expect from dilution of the gasoline with 11% to 15% MTBE and lowering the concentration of benzene until its concentration is 1%. "Dilution" to achieve emissions reduction is legitimate as long as energy-content change and possible new toxics in the emissions such as MTBE and formaldehyde are evaluated. According to the EPA, the much-touted reduction of benzene emissions in RFG is due, not to MTBE, but to the reduction of benzene in the fuel formula; and with 15%-MTBE fuels, formaldehyde emissions increase between 27% and 200%, depending on the type of vehicle emission-controls.{12.3 The Complex Model predicts that NOx will be increased by the addition of MTBE.{12.4
The COMMITTEE may also wish to examine the common practice of gasoline octane-enhancement through the use of MTBE. Garrett et al have observed:
"Octane enhancement without additives is possible (DOE [U.S. Department of Energy], 1985). It is achieved by "reforming" some of the components of the distillate during the refining process so that the refined gasoline already has sufficient octane. Some producers prefer this "reformate" method of obtaining the required octane, and it does not have the environmental disadvantages of MTBE or its alcoholic [ethanol and methanol] competitors."{12.5
According to the Maine Department of Environmental Protection (MDEP), oxygenated gasolines are not required by the Clean Air Act to be used in Maine.{12.6 "Reformulated gasoline is not, and never has been a Federal requirement for Maine. The McKernan Administration `opted in' to the Federal reformulated gasoline program on June 26, 1991 through the opt-in provisions in Section 211(k)(6) of the 1990 Clean Air Act Amendments. ... the Department [MDEP, as of July 13, 1995] continues to support the Federal reformulated fuels program and believes it offers significant VOC and air-toxics reduction benefits."{13.1 [Underline, JCH]
Evidence cited above argues this "belief" to be questionable. But MDEP officials are still promoting a scientifically unjustifiable program that benefits financially the oxyfuels industry in particular, and polluting industry in general. By passing the blame for bad air on to ordinary taxpayers and owners of automobiles, the State proclaims its support for clean air and creates an image of the State as a champion of good environmental politics.
A most cruel adage promoted by the State, as well as by many well-meaning citizens, is that through CARTEST and oxygenated RFG, each citizen "can do his part". What some folks who repeat this mantra may not realize is that polluters are convincing others to spend money in a less-than-effective effort to clean up bad air. This takes the pressure off polluters so that polluters can avoid doing their part. And bad air stays bad, or gets worse.
Although Federal Law defines reformulated gasoline as containing an oxygenate, it is not a requirement if addition of the oxygenate raises the emission of ozone-producing NOx over the NOx-emission level of a federally- defined baseline gasoline.{13.1.1
The 1997 Final Report by the oil and automobile manufacturers on their Air Quality Improvement Program finds that, when added to low-aromatic fuels, oxygenates increase NOx emissions. [Low-aromatic fuels lower the combustion emissions of toxic gases.]{13.2
In the face of such evidence it is legitimate to raise the question of why the USEPA has not restricted the use of oxygenates like MTBE in gasoline. Such questions have been raised, but the EPA has avoided a direct answer by arguing the questionable assertion that the EPA computer model predicts overall lowered NOx emissions from the model's fleet of automobiles.{13.3 The real answer may have less to do with science and public health -- than with politics.
The preponderance of evidence argues against MTBE's ability to reduce ozone; because MTBE can increase NOx, MTBE may actually be raising the level of ozone.
The COMMITTEE has heard many witnesses explain why they feel they and others are suffering, often severely, from oxygenated RFG.{13.4 Peter Joseph is one of them. Professor of Radiologic Physics at the Hospital of the University of Pennsylvania, he reports an "explosive" rise of asthma among children in the Philadelphia area. Joseph says his investigations show the need for serious epidemiological studies on asthma. He feels that gasoline oxygenate MTBE and its atmospheric reaction products should be studied as possible contributing causes of asthma.{13.5
So if oxygenated fuel is not required, why are we using it? The answer is that Maine officials rushed to adopt an MTBE fuel without sufficient thought. The COMMITTEE hearings have demonstrated this. What our officials might consider at this time would be to simply go to a cleaner gasoline -- without oxygenates. Who would object to the advantages of reformulating a gasoline with low sulphur, low vapor pressure, less benzene, and no oxygenate -- to produce less NOx, and less formaldehyde? RFG is controversial, not because it's reformulated, but because it comes packaged with an oxygenate -- MTBE.
MDEP's claim that "Reformulated gasoline yields aggregate toxic emission levels well below non-reformulated fuels"{13.6 is misleading in view of industry test results,{13.7 and in view of what is needed to clean up ozone in Maine.
In May 1995, the Governor's Task Force Study on the Health Effects of Reformulated Gasoline published its report. It contained inaccurate information about the efficacy of VOC control of ozone in Maine.
Within about a month's time, the MDEP changed captions on some (not all) of its previously misleading pie charts to reflect the fact that MDEP considers only man-made VOCs when it talks about VOC-reduction goals.{13.8 But still, MDEP did not graph figures on actual (total) VOC emissions that affect ozone production. On June 28, 1995, when MDEP presented a new pie chart to the Board of Environmental Protection at a public hearing,{13.9 the chart was once again missing proper notation; the misinformation about the State's VOC program had become a well-established falsehood.
While the COMMITTEE was hearing testimony from citizens on the health effects of oxygenated fuel, MDEP Commissioner Edward O. Sullivan began action to limit public participation in an ongoing study of the possible expansion of mandatory RFG use into non-RFG areas of the State.{13.10 (the study had been ordered by the Legislature.{13.11) Sullivan contacted the USEPA on this matter,{13.12 and he established a list of eight "affected parties", a roster that excluded the Health Bureau, the COMMITTEE, and persons or organizations who have questioned the effectiveness of RFG or who oppose its use. This select group of "stakeholders" included only RFG advocates.{13.13
Although the American Lung Association of Maine (ALAM) has supported RFG as an ozone-reduction strategy, ALAM is understandably concerned at the considerable public testimony about health effects attributed to the oxygenate MTBE. Consequently, the ALAM informed MDEP that it does "not understand the logic behind Sullivan's selection of "affected parties"" and that "the American Lung Association of Maine will not be a part of any formal meeting on this subject that excludes... affected parties who have voiced concern".{13.14
The ALAM also asked that the MDEP "ensure that the intended pollution reductions from reformulated gasoline are actually being achieved" and that the State Bureau of Health continue "research into the health impacts of RFG on both healthy and sensitive populations." {13.15
The ALAM letter to MDEP seemed to have an effect on Sullivan. Within a few days, Sullivan revised the list of eight affected parties by adding the names of Julian Holmes and Ralph Stevens.{13.16 A consensus of participants at the first and, to date, only gathering of the study panel (November 4, 1996) found the proposal to use oxygenated fuel statewide to be contrary to current interpretation of the Clean Air Act.{13.17
Next, Sullivan drafted recommendations to the State Legislature the general thrust of which was to create an image of RFG as beneficial to the cause of reducing air-pollution in Maine, a position the study panel had not endorsed. In fact, several panel members had suggested that the value of oxygenated fuel in reducing air pollution be established prior to discussions of expanding its use in Maine.{13.18 As a study-panel member, I prepared a critique of the Sullivan draft.{13.19
Commissioner Sullivan's confidence in oxygenated fuel seems to be based on overly optimistic claims about Maine's air-pollution reduction program. In a public statement to the Select Committee (COMMITTEE) on July 25, 1996{13.20 he:
* stated the contribution of highway mobile sources to Maine's VOC inventory as being 45%. (p.1, par.2)
[In contrast, the official MDEP number for Maine is less than 4%.{13.21 In the most polluted county (Cumberland), the official MDEP figure for mobile source contribution to the county's total VOC emissions is only 16%.{13.22 In fact, the major claim to legitimacy of Maine's ozone- reduction program lies in misrepresentation of VOC levels.]
* characterized Maine's participation in the RFG program as being in response to a "basic" requirement of the Clean Air Act (CAA). (p.2, par.3)
[In fact, it is "basic" in that the primary purpose of the CAA requirement is to reduce ozone to below the federal ozone standard. Maine's RFG program will not contribute substantially toward this goal.{14.1]
* failed to inform the COMMITTEE that Maine's use of oxygenated fuel was not the only way to avoid "Federal sanctions" (p.2, par.4).{14.2
* cited VOCs as an important factor in ozone control "in urbanized areas such as southern Maine". (p.3, par.2)
[Sullivan provided no sources for this statement, and cited no figures as to how much his oxygenated fuel program will reduce ozone. Nor did Sullivan say how his program will reduce ozone in eastern, coastal, and southern-rural Maine -- areas where air is sometimes very bad.]
* said, "RFG benefits outweighed questions and costs".{14.3
[I have since asked Commissioner Sullivan what he meant by this, and he told me the comparison was between human "exposure levels to MTBE" compared to the exposure "related to ozone", had MTBE not been used to control ozone.{14.4]
* said he "looked at a non-MTBE alternative and was disappointed in the results".{14.5
In other words, instead of first looking into fuel formulations, MDEP first picked the fuel and then went on to craft a plan that requires non- mobile sources of man-made VOCs to make up the remainder of the 15% VOC reduction demanded by the EPA, a plan that probably isn't effective in meeting ozone-reduction requirements.]
* maintained that RFG reduces NOx, a claim he says is "per USEPA". (p.3, par.3)
[In this case, USEPA apparently claims pollution-reduction capabilities that are not always confirmed by actual measurements.{14.6]
* said that a significant benefit of RFG is that it is "the single largest element of our [emissions-control] plan ...". [underlining, JCH] (p.3, par.3)
[MDEP has previously disclosed that the "significance" of the RFG program is "limited"{15.1 and "insignificant".{15.2]
* cited the Governor's Task Force on the Health Effects of Reformulated Gasoline as justification for the RFG program. (p.4, last par.)
[In fact, some persons on the Task Force{15.3 did not understand that the effectiveness of the program was quite limited.]
* suggested "enhanced auto emissions testing" [CARTEST] as an alternative to the RFG program. (p.5, par.3)
[Sullivan did not address the question of whether CARTEST, like oxygenated fuel, is likely to be effective in reducing ozone pollution in Maine.{15.4]
* said, "Governor King and I feel that it [use of RFG] should be limited for now to non-attainment areas, but I'd prefer a single fuel". When questioned by Senator Harriman as to whether RFG should be used statewide, Sullivan responded, "We have a very high biogenics contribution to VOCs in northern part of State, so VOC control will have no benefit". Sullivan also said that in Vermont, "they are prohibited from using RFG because they are in attainment".
[Subsequently, Sullivan has told me that because it is a federal matter, he is doing "nothing" to restrict the sale of oxygenated RFG in Maine to non-attainment areas.{15.5]
* said, in response to a question from Rep. Glenys Lovett about possibly higher formaldehyde emissions from MTBE gasoline, "That's debatable".
[This statement should be examined in light of the evidence.{15.6]
* claimed MTBE is not as significant a concern as benzene. He said MTBE is 92 times as soluble in water as toluene, 300 times as soluble as xylene, 27 times as soluble as benzene, and that MTBE degrades more slowly than other gasoline components.{15.7
[MDEP Hydro-geologist Bruce Hunter told the COMMITTEE, "MTBE is 1/10 as toxic as benzene. ... In RFG, MTBE is 11 to 15%; benzene 1%". {15.8) Now using Sullivan's and Hunter's numbers (27 x 1/10 x 11%/1% = 30), it appears that MTBE in water could be 30 times as dangerous as benzene -- assuming that relative solubility and toxicity are environmental-health concerns.
I later asked Sullivan for a source for his statement that MTBE was not as significant a health concern as benzene. He said he relied on Phil Haines (then Acting Director, Maine Health Bureau) for this information.{15.10 In February 1996, Sullivan said, "I think there are people who are hypersensitive to RFG, as there are people who are sensitive and allergic to penicillin or other substances".{15.11 Does Sullivan believe that mandatory exposure to MTBE is analogous to voluntary use of penicillin?]
In response to a question (from Representative Lovett) about testing for atmospheric toxics, Sullivan's Chief of Mobile Sources, Ron Severance, told the COMMITTEE, "I'll defer to others -- we don't do testing; we rely on the RFG Hotline -- ARCO".{15.12
In May, 1995, Sullivan told a Congressional Committee "...that certain provisions of the Clean Air Act Amendments of 1990 do not make sense for Maine -- that they are grounded in neither good science nor common sense". Sullivan criticized the EPA's "rigid position" on CARTEST's "intrusive, inequitable, and potentially absolute [VOC-reduction] testing technology".{15.13 But in the next breath, Sullivan praised EPA's "flexibility and commitment" to help Maine implement oxygenated fuel.{15.14
Sullivan's performance on air-pollution should be examined in the light of the recent disclosure of (unreported) high levels of (coPCB) water-pollution in Maine rivers.{16.1 The Augusta Capital Weekly reported that, subsequent to requests from paper companies, MDEP Commissioner Sullivan "removed those portions of the state's dioxin monitoring report that discussed fish contamination from co-planar polychlorinated biphenyls, a dioxin-related compound". These discoveries could have been published in May, 1996; Sullivan planned not to publish the test results until later. In a letter to me dated September 18, 1996, Sullivan accused the Capital Weekly of publishing false information about the MDEP role in this matter. Sullivan's letter asserts that an April 1996 MDEP publication "contained a full disclosure of elevated levels of coplanar PCBs".
But that publication presents only 1994 data and does not deal with the levels of total PCBs measured in 1995 that resulted in the 1996 Capital Weekly disclosures. Industrial pressure on the MDEP is not confined to matters of dirty air. Dirty water is also high-level politics.
A milestone in the State's program to control ozone with oxygenated fuel was the Governor's Task Force Study on the health effects of RFG fuel that uses MTBE as its oxygenate.{16.2 I have testified that the Task Force Study may have served well the politics of accommodation; but that as a scientific argument, it is lacking.{16.3
The ostensible purpose of the Study was to evaluate health complaints linked to RFG, and to compare the possible health effects of RFG gasoline with those of conventional gasoline. Neither of these goals was accomplished. This is not to say the conclusions are faulty; it is to say, however, that the Study does not justify them.
The credulity of the Task Force accosts the reader of the Study on its very Introduction Page. That the Task Force would introduce itself by proclaiming its own "high levels of credibility and expertise" (p.9, par.3) was perhaps an attempt to counterbalance the generally ineffectual report that followed -- a study completed in less than two months, and commenced under a three-week deadline.{16.4
Opening with an unqualified acclaim for the benefits of RFG gasoline and its ability to reduce ozone-producing volatile organic compounds (VOCs), the Study misstates official Maine VOC figures by telling us that "almost 60%" of the (ozone producing) VOCs from seven southern counties come from mobile sources there, and that "while some ozone is transported from elsewhere, a larger amount is also formed within our borders". (p.11)
In contrast to these Task Force assertions, the official MDEP Inventory of VOCs shows that, in the seven southern counties cited, only 16% of VOCs are from mobile sources (not "almost 60%"), and only 12% are from highway mobile sources{17.1; the MDEP Annual Report on Air Quality finds "the majority" of ozone in Maine comes from outside the State;{17.2 and the Commissioner of Environmental Protection says the figure is 80%.{17.3
The possibility of its errors being considered inadvertent was dashed by the Task Force capping off its discussion of ozone and VOCs with a full-page VOC pie-chart. It showed motor vehicles as responsible for 58% of the VOC "emissions pie" for the state's seven southern counties! (p.12)
The Study ignores the MDEP finding that Maine is probably a Nitrogen Oxides (NOx)-limited region rather than VOC-limited.{17.4 And there is no mention of the possible health consequence of choosing the wrong pollutant (ozone precursor) on which to expend our time and money.
Although on page 7 of the Study the Task Force was mildly critical of computer modeling, this same task force may have been less critical of one model when the result was "acceptable". This modeling technique was used by the EPA to compare the amounts of combustion products (pollutants) produced by regular gasoline and oxygenated RFG, and the modeling results appear in the table on page 13 of the Study. The modeling predicts that oxygenated RFG produces fewer pollutants, including NOx, when compared to regular gasoline. A table identical to that on page 13 appears on an information sheet published by the Oxygenated-Fuels Association.{17.5
The Clean Air Act requires that RFG gasoline have no more NOx emission than regular gasoline, and some industry measurements of oxygenated-RFG combustion suggest that NOx emission therefrom may be higher than from some non- oxygenated gasoline.{17.6 There is no discussion of such measurements in the Task Force Study.
Benzene and formaldehyde are carcinogens, but formaldehyde does not appear in the pollutant table (p.13), even though the Task Force reports that formaldehyde concentration in automobile exhaust may be increased by the MTBE oxygenate. (p.16) The current OSHA standard 15-minute exposure limit for formaldehyde is 2 ppm, while that for benzene is 5 ppm.{17.7
The Task Force cites no data that might not support its blanket assertion on emissions: "Adding MTBE decreases tailpipe emissions of carbon monoxide, benzene, toluene, and VOCs."(p.16) For instance, one recent industry comparison-testing of non-MTBE against MTBE fuel finds evidence of MTBE gasoline inferiority, but finds it to be statistically insignificant.{17.8
The above-cited pollutant table (p.13) claims that use of RFG lowers particulate matter in automotive emissions. The RFG HOTLINE makes the same claim.{17.8.1 I asked EPA's Robert Judge whether he could direct me to measurements to confirm this claim. He referred me to Lester Wyborney at the EPA National Vehicle and Fuel Emissions Laboratory in Ann Arbor, Michigan. Wyborney said that as far as he was aware, EPA had not made such measurements, that EPA did not have the resources to measure MTBE decomposition products or toxics that might be associated with "neurological or acute effects" in humans, but that EPA was in the process of evaluating measurements of MTBE itself in automotive exhaust.
Nor was the RFG HOTLINE able to find data on measurements of particulate pollutant emissions from RFG versus conventional fuels.{17.9 HOTLINE Director Charlene Garland told me that the industry claim for particulate reduction with RFG was based on predictions utilizing the EPA PART-5 Model (particulates) and the EPA Complex Model for automotive gaseous emissions.
R. Neal Olson (Utah State Department of Environmental Quality) measured air-borne particulates in Salt Lake and Utah Counties during the winter of 1994-5. That winter, Salt Lake County, a CO-afflicted oxygenated-fuel county, had obtained an EPA waiver to use non-oxygenated gasoline for two months -- because of a "reported increase of particulates associated with oxygenate use during the winter of 1992-3". Olson had prepared an experiment to measure airborne particulates during two periods -- one when oxygenated gasoline was in use, and the other when it was not. The results were non-conclusive, compromised by uncooperative weather; but there was some increase of particulates when oxygenates were used.{17.10 Olson believes we should take particulate pollution seriously. He has authored a study that uses conventional equipment to measure particulate pollution under EPA's newly proposed rule on fine particulates.{17.11
The Health Effects Institute (HEI) has issued a sobering comparison: that the estimated cancer threat from particulate air-pollution in a single city (Philadelphia) is greater than the cancer threat from benzene air-pollution in the entire United States.{17.12 The COMMITTEE may wish to consider the relative importance of benzene pollution so heavily emphasized by advocates of oxygenated RFG. Dr. Ted Shettler, of Physicians for Social Responsibility, says that although the number of premature deaths triggered by particulate pollution seems "compelling, it's important to recognize that there's a much larger population that is experiencing health effects resulting from this exposure".{17.13 The ALAM child-asthma map of Maine{17.14 should be kept in mind, not just for the pollutant "at hand", be it benzene, MTBE, ozone, or particulates, but as a warning to all of us that there are many pollutants around and that some of them may be serious!
The above detour into particulate pollution illustrates one aspect of the superficiality of the Task Force Study. Another example of lack of serious intellectual involvement is the Task Force citing "difficulty" in assessing complaints of health problems attributed to RFG. The reason:
"complaints began after January 1995 while most, if not all, service stations in southern Maine began distributing 11% MTBE RFG to their customers in early December 1994". (p.11)
This statement should be compared with a subsequent declaration:
"Toxicity associated with inhalation of gasoline vapors is typically found at high exposure levels, however, exposure to lower levels over long periods of time can produce similar results". (p.14)
The Task Force cannot have it both ways and expect only instant symptoms from RFG, while conceding delayed symptoms from regular gasoline. [underlining, JCH]
The Task Force declares that studies of kidney tumors in male rats "have been criticized for lack of controls comparing MTBE to gasoline". (p.18, par.1) No explanation of, or citation for, this criticism is identified.
The Task Force suggests that MTBE is a "low potency potential carcinogen" compared to "higher potency carcinogens" that MTBE dilutes when it is added to gasoline -- but adds that "no animal data is available to test this hypothesis". (p.18)
The Study lists MTBE effects or lack of such on animals, but finds "there is no human data available on the chronic effects of MTBE ... or on human cancer risk from MTBE", and that "there is no data on the toxicity of MTBE in combination with the other constituents in gasoline". (p.17) In other words, we haven't compared the relative toxic effects of MTBE in gasoline and its combustion products with those of non-MTBE gasoline.
On the very day the Task Force was appointed, Robert E. Wages, President of the Oil, Chemical, and Atomic Workers International Union (AFL-CIO), wrote to Oxygenated Fuels Association Director Fred Craft:
"Your statement that "EPA found no scientific evidence to support claims that MTBE causes headaches, dizziness, and nausea" is contrary to complaints recently received from a tremendous number of our members, as well as many thousands of motorists exposed to a very low level of gasoline containing MTBE."{18.1
I have tried (unsuccessfully) to understand what is germane about the concluding observation of the Task Force Summary of Cancer Risk which reads:
"Comparison of the overall risk of cancer incidence caused by cigarette smoking versus cancer risk from all air pollution is approximately 10 to 1 (Pope). Since the net effect of RFG would be to decrease air pollution, the relative risk of cancer from air pollution should theoretically decrease over time". (p.18)
Regarding the 48 responses to a Task Force survey of Maine residents, the Task Force comments: "The results clearly demonstrate the existence of a human response to an exposure to RFG containing methyl tertiary butyl ether (MTBE) among the consumers submitting the Oxygenated Fuel Health Surveys, but there is no comparison with symptoms for regular gasoline exposure". (p.34)
The Task Force Study addresses MTBE pollution of groundwater in a single brief paragraph which:
(a) cites U.S. Geological Survey measurements in Colorado that found MTBE in groundwater at 80% of the thirty measurement sites. These measurements are characterized as a "limited experience which cannot be used to draw any useful conclusions for Maine ..." (p.24) and
(b) claims MTBE "has become a reliable marker" of gasoline contamination from leaking underground storage tanks. (p.24)
The Colorado measurements are all but dismissed with the parting advice that "more" MTBE surveillance and monitoring is needed in Maine; there is no discussion of current MTBE-monitoring of Maine's waters. Nor does the Task Force explain how MTBE serves as a "reliable marker" of underground gasoline leakage.
In fact, MTBE is soluble in water; and unlike other constituents of gasoline, MTBE does not adsorb on soil particles; and according to the Santa Clara Valley (California) Water District, MTBE can separate itself from a gasoline spill and become a "detached plume" of pure MTBE and groundwater. "And unlike solvents that more than a decade ago were detected in ground water, MTBE leaves no telltale sign on the surface of the earth, making it harder to find."{18.2 Thus, in contrast to the Maine Task Force claim, MTBE can be a particularly unreliable marker of gasoline leakage.
Directly counter to the Task Force claim that MTBE is a "reliable marker" of gasoline contamination is a published paper by three geologists (at the University of Maine and at the MDEP) which states:
"Several colleagues have commented that MTBE may be useful as a contaminant tracer because it is apparently less toxic, and precedes and travels further than the BTX components [benzene, toluene, xylene]. We beg to differ. That opinion forgets the human element of gasoline spills.
"The North Berwick [Maine] spill contaminated the wells of two homes to concentrations an order of magnitude higher than if there had been no MTBE. The young couple in one of those homes had to wait for us to invent a whole new method of water treatment for their household supply. The young family in the other decided that water treatment was not the way to go, and chose instead to truck in water, at considerable expense and nuisance. The fact that MTBE appears to be less toxic than benzene was no consolation to the parents of young children. The anguish these two families underwent cannot be put into words."{18.2.1
It is worthy of note that the Santa Clara Valley Water District (Santa Clara County) takes MTBE contamination very seriously. The Water District recommends that, because of MTBE's behavior in ground water, "all groundwater cases with MTBE be considered emergency sites", and that "it is imperative to investigate, delineate, and remediate these plumes very promptly, before it becomes impossible to determine the origin ... Gasoline additives, particularly Methyl Tertiary Butyl Ether (MTBE), pose a serious threat to groundwater resources."{18.3
The Task Force Study condones the use of MTBE-RFG in Maine, and advises people who don't like it to obtain fuel "at service stations where gasoline can be pumped for the customer" (p.25). Although some might question a Health Bureau policy that recommends not exposing oneself to a toxic substance if other persons are willing, or paid, to expose themselves instead, nonetheless, some final recommendations of the Task Force are worthy of consideration:
The very last page (p.40) of the Study lists "Personal Contacts by Task Force Members". Excluding EPA and state officials, eight persons are named. Seven of them are listed with affiliations; one, Myron Mehlman, is not. Of the eight, the Task Force identified only three as having ARCO affiliation. Thus, from the Task Force identification of its non-government contacts, one might reasonably assume that most of those contacts were not affiliated with ARCO. Actually 7 out of 8 (Mehlman the exception) have been ARCO affiliated.
All told, the Task Force Report, which promotes oxygenated RFG as having "a modest potential for long-term positive health impacts" (p.7) is short of rudimentary scientific discipline.
There is an aspect of the Task Force Report of which the COMMITTEE should be particularly aware, namely that the therein unidentified Professor Myron Mehlman, the non-ARCO-affiliated "contact" (p.40), is something of a folk-hero among clean-air advocates. As North American Secretary of the Collegium Ramazzini, Mehlman is a signatory to the September 1993 Collegium declaration that endorsed the limiting of workplace benzene exposure to .1 ppm TLV-TWA [Threshold Limit Value - Time Weighted Average] in air, a value recommended in 1990 by the American Conference of Governmental Industrial Hygienists.{19.1
As Director of Toxicology at the Mobil Oil Corporation, Mehlman participated in a 1989 symposium on environmental health issues and risk assessment held in Japan, where he learned that Mobil-owned affiliate MSKK was producing gasoline with a benzene level of 5.7%. Mehlman insisted that Mobil lower the benzene level. Mobil said it would cost too much and terminated Mehlman's employment for cause; Mehlman sued. He has won a $3.4 million judgment against Mobil for his financial losses as well as a $3.5 million punitive judgment. The appeals court concluded that "the punitive damages award was a "necessary deterrent" to prevent companies like Mobil from silencing employees who object to conduct that has a great potential for harm to many people".{19.2
Mehlman is Adjunct Professor of Environmental and Community Medicine, University of Medicine & Dentistry of New Jersey, Robert Wood Johnson Medical School, Piscataway, NJ. Mehlman has held positions as: Chief of Biochemical Toxicology, U.S. Food and Drug Administration; Special Assistant for Toxicology and Environmental Affairs, Office of the Assistant Secretary for Health; Associate Professor of Biochemistry, Rutgers University; Professor of Biochemistry, Nebraska College of Medicine; and Director of Toxicology, Mobil Oil Corporation. He is a Fellow of the American College of Toxicology, of which he was Founder and President. He is Editor of The Journal of Toxicology and Industrial Health, and an Associate Editor of the International Journal of Occupational Medicine and Toxicology. He is a visiting scientist at the Agency for Toxic Substances and Disease Registry (ATSDR).
In testimony before the New Jersey Senate, Mehlman has asked that use of MTBE and other such additives be prohibited in gasoline until they have been adequately tested.{19.3 Mehlman argues MTBE cancers are similar to those caused by exposures to comparable doses of benzene, vinyl chloride, and 1,3- butadiene.{19.4 He has petitioned USEPA Secretary Carol Browner to classify MTBE as a probable human carcinogen, and asked for the lowering of the health- advisory level for MTBE in drinking water to 5 ppb -- the same as for benzene.{19.5 The Collegium Ramazzini has determined that "exposure to MTBE in gasoline should be avoided in order to prevent needless illnesses of both consumers and workers... and urges that the toxicity of MTBE be fully and vigorously examined".{19.6
In 1978 Mehlman's claim that cigarettes cause cancer{19.7 was criticized by Tobacco Institute Vice President William Kloepfer who claimed that the tobacco industry is "confounded with constant charges of carcinogenicity of our products. I think it is unbecoming for our defenses to be mounted in the field of conjecture, rather than facts".{20.1
Some MTBE advocates have raised questions about the relevancy of certain animal research to the carcinogenic potential of MTBE.{20.2 At the request of Ralph Stevens of South Berwick, Mehlman prepared a response to the September 24, 1996 testimony of Elihu York to the COMMITTEE. It is a monograph on animal research, cancer, and MTBE,{20.3 which the COMMITTEE may find useful in its review of questions raised. He has since completed a more extensive treatise on MTBE which he submitted in support of his request that the EPA lower the health advisory level for MTBE in water.{20.4
Philip Haines, Acting Director of the Maine Bureau of Health, told the COMMITTEE on July 25, 1996 that he'd "rather deal with MTBE than benzene ... that benzene is "60 times as potent" as MTBE".{20.5 If one replaces Bruce Hunter's figure of "10" with Haines' figure of "60"{20.6 (in the arithmetic on page 37 above), might MTBE still be 5 times as dangerous as benzene?
To a question from Representative Glenys Lovett about possibly higher formaldehyde emissions from MTBE gasoline, Haines responded, "It's the exposure that counts".{20.7
If it's "exposure", then it's reasonable to ask why Haines did not discuss items such as the following that are relevant to Rep. Lovett's question:
Haines also discussed the National Research Council Report on Oxygenated Motor Vehicle Fuels, but did not discuss the Report's specific findings that:
Nor do I recall Haines informing the COMMITTEE that "most of the information on MTBE health effects has come from a program of testing conducted under a 1987 negotiated, enforceable, consent agreement between EPA and the Oxygenated Fuels Association (OFA), which provided several studies on the inhalation toxicity of MTBE in laboratory animals."{20.13
In a telephone conversation, Haines told me he believed the statements about Maine VOCs "were true at the time" the Task Force Study was written, but he did not wish to meet with me and discuss the matter further.{20.14 Haines did not seem to understand the basics of ozone-production chemistry, or the limitations of VOC-control to reduce ozone in Maine. A letter from Haines following our conversation suggests less than a vital involvement in the whole issue of oxygenated fuels and ozone reduction.{20.15
The COMMITTEE should note that with regard to disclosure of high-levels of PCBs in Maine rivers,{20.16 Haines did not plan to publish the test results until later. The Kennebec Journal reports Haines as saying, "We believe the health protections will be well taken care of" with a public health advisory about the human health risk -- likely to be issued in December [1996].{20.17
Haines then issued a press release setting back the publication date until spring 1997.{20.18 It reads, "the [health] advisories are being re-emphasized at this time in light of the recent data. Cancer risk has also been considered. The incremental cancer risk resulting from consumption of fish for the period between now and the start of the 1997 open water fishing season is negligible."
With respect to the Presumpscot, Salmon Falls, and Sebasticook rivers, the current Health Bureau advisory is for mercury in lakes and ponds -- not for PCBs in rivers.{21.1 I asked two members of the Health Bureau staff why the Bureau considered the existing warning to be adequate. The answer I got in each case was that a single warning should be sufficient.
That response is like warning swimmers against sharks without telling them where the sharks are, and without warning them at all about the equally dangerous undertow. I have been unable to find out from the Health Bureau where warnings are posted on the above-named rivers.
The Capital Weekly newspaper editorialized about this matter as follows:
FAILING THE PUBLIC TRUST
"The state's health and environmental officials did a gross disservice to the people of Maine, especially its anglers, by failing to inform them that unhealthy amounts of a dioxin- like chemical are present in Maine rivers."{21.2
And with respect to Health Bureau warnings for mercury pollution, a four- part series of articles on "The Mercury Menace" by the Portland Press Herald and Maine Sunday Telegram reported:
"Three years have passed since the state first issued a mercury-related fish consumption warning for all Maine lakes and ponds. But the Portland Press Herald and Maine Sunday Telegram found that public health officials are not getting that message across to residents and tourists alike."{21.2.1
It may be of interest to the COMMITTEE that on December 27, 1996, I asked Haines' successor as Health Bureau Chief, Dora Mills, and MDEP Commissioner, Edward Sullivan, what has been done to implement the RFG Task Force recommendation for "increased surveillance" of MTBE in ground water.{21.3 I had been informed separately by two top Health Bureau officials that, respectively, "nothing" and "absolutely nothing" have been done about the Task Force recommendation for increased MTBE surveillance. An MDEP official had observed, "at this stage it is unlikely that we will monitor any surface waters or shallow wells [for MTBE] in the state".{21.3.1
On January 23, 1997 I sent a letter to Sullivan reminding him of my request of December 27.{21.4 Sullivan prepared a response to me, dated January 3 and mailed on January 24, but did not address my question about MDEP response to the Task Force recommendation.{21.5 On January 27 I wrote to Sullivan inviting him again to comment on my request of December 27. His response of February 7 implied that MDEP itself made no response to the Task Force recommendation, but that the Health Bureau had provided me (JCH) with "the state's response".{21.6 That response is described in the paragraph below.
Mills' response to my letter was dated January 28 and was signed by Philip Haines.{21.7 It described an MTBE water-measurement program that "should begin this spring" -- about two years after the Task Force (on which Haines served), made its recommendation to "increase surveillance" for MTBE. I wrote to Mills asking "what kind of action you feel the Task Force had in mind when it recommended increased MTBE surveillance, ... how the Bureau's proposed "increased" MTBE surveillance differs from the level of that being carried out today, ... and what action the Health Bureau may have taken on the six other Task Force recommendations".{21.8 By letter of February 12, Mills described the MTBE surveillance program (see Haines, note 21.7 above) to begin this spring.{21.9
Task Force member Lee Ann Baggot told me that at concentrations to which humans are subjected, there is low risk of MTBE carcinogenicity. She said results of animal cancer studies cannot always be extrapolated to humans, and that there were yet to be conducted good double-blind studies with humans on the carcinogenicity of MTBE. I asked if she felt such a study could be engineered, and she replied that "it could be done, but it would be expensive". I asked if she knew about Myron Mehlman, and she said she had contacted him and that "he seemed to be doing MTBE as a hobby".{21.10
Richard Greves was a Task Force member from the MDEP. I asked him if the Task Force had specifically discussed the scientific viewpoint that Maine's 15% VOC reduction program (using RFG as its "cornerstone") was not going to do much toward meeting the federal requirement to reduce ozone. He said he did not know of my report{21.11 until after he had left the Task Force. Apparently no one brought it to the attention of the Task Force, or even informed it that Maine's VOC program has little chance of reducing ozone.
I mentioned to Greves the statement on page 11 of the Task Force Study: "Mobile source emissions of VOCs account for almost 60% of all the VOCs emitted in the Maine Counties with the most serious air pollution problems ...". I asked why the Task Force Report included a pie chart (page 12) that reported mobile sources to account for 58% of Maine VOC emissions in the seven southern counties -- when the actual number, calculated from MDEP tables, was 16%.{21.12 Greves responded that the Report was not deliberately misleading because it was customary at MDEP to refer to man-made VOCs only.
Greves said, "reformulated gas was the paradigm we were working with. We did not discuss anything other than oxygenated gasoline. We looked at the Mobile 5 model and we compared the MTBE gasoline to regular gasoline."
Greves said he was unaware that any questions were raised as to whether there were alternatives to MTBE or to oxygenates. He assumed that the oxygenate solution was simply provided to the Task Force by the EPA -- and by the Governor.{22.1
Greves remarked that the representatives to the Task Force from Coloradans for Clean Air seemed to be "well funded". I asked if anyone on the Task Force asked who the "Coloradans" were; and Greves said, "They were just like a lobby in Maine -- like the NRCM [Natural Resources Council of Maine] or the Lung Association".
Task Force member Ronald Deprez is President of the Public Health Resource Group, an organization that provides hospitals and health providers with research on services needed in communities. I asked him if the Task Force had considered formulations of gasolines other than the one chosen by the State. He answered that there were no studies by the Task Force on other than the gasoline "which was before us ... no research was done on anything else."{22.2
Health Bureau toxicologist and Task Force member Philip Kemp told me that, except for Myron Mehlman and Barbara Charnes, all industry and association consultants ("Contacts") listed in the Task Force Report were associated with ARCO! [In fact, Charnes is also.{22.2.1] I asked if the Task Force studied any gasoline formulation other than one using MTBE. He said he "understood that MDEP did" but that the Task Force discussed only the MTBE formulation which was proposed to the Task Force by MDEP. Kemp says Task Force contacts Jonathan Borak and David Gray each visited with the Task Force here in Maine, that they represented ARCO, and that Borak and Gray, not the Task Force, initiated the first contacts.{22.3
Lani Graham, then Director of the Bureau of Health, was chair of the Task Force. In a letter to Ralph Stevens of South Berwick, Graham was dismissive of concerns about MTBE safety.{22.4
But oddly enough, Graham's RFG Task Force had cited in its Study (p.22) a finding, by investigators at the Centers for Disease Control (CDC), that blood samples from residents of Fairbanks, Alaska showed elevated levels of MTBE during the period when oxygenated fuel was tried in Fairbanks.{22.5 In a letter to the Alaska Commissioner of Environmental Protection, CDC scientist Ruth Etzel was less dismissive than Graham of MTBE safety. Etzel summarized the CDC findings:
"Persons with higher blood levels of MTBE more frequently reported symptoms, including headache, nausea, burning of the nose and throat, and spaciness, compared with those with lower blood levels of MTBE.
"Exposure to gasoline without MTBE did not result in increased symptoms.
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